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91.
Textured surface is commonly used to enhance the efficiency of silicon solar cells by reducing the overall reflectance and improving the light scattering. In this study, a comparison between isotropic and anisotropic etching methods was investigated. The deep funnel shaped structures with high aspect ratio are proposed for better light trapping with low reflectance in crystalline silicon solar cells. The anisotropic metal assisted chemical etching (MACE) was used to form the funnel shaped structures with various aspect ratios. The funnel shaped structures showed an average reflectance of 14.75% while it was 15.77% for the pillar shaped structures. The average reflectance was further reduced to 9.49% using deep funnel shaped structures with an aspect ratio of 1:1.18. The deep funnel shaped structures with high aspect ratios can be employed for high performance of crystalline silicon solar cells. 相似文献
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中低品位磷矿高效清洁综合利用是中国基础磷化工产业发展中遇到的共性瓶颈问题。以中低品位磷矿磷-钙-镁一体化综合利用中试成果为基础,通过创新集成技术对中低品位磷矿直接进行处理,获得高品质磷精矿[w(P2O5)≥36%、w(MgO)≤0.5%]可用于任何湿法磷酸及热法黄磷生产工艺,同时回收高附加值的氢氧化镁和轻质碳酸钙。该工艺磷全部回收、无尾矿产生、实现了废水近零排放,项目的实施对推动中国磷化工产业可持续发展及从源头解决“三磷”问题具有重要意义。 相似文献
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Jonathan K. Dozier Mark D. Distefano 《International journal of molecular sciences》2015,16(10):25831-25864
The use of proteins as therapeutics has a long history and is becoming ever more common in modern medicine. While the number of protein-based drugs is growing every year, significant problems still remain with their use. Among these problems are rapid degradation and excretion from patients, thus requiring frequent dosing, which in turn increases the chances for an immunological response as well as increasing the cost of therapy. One of the main strategies to alleviate these problems is to link a polyethylene glycol (PEG) group to the protein of interest. This process, called PEGylation, has grown dramatically in recent years resulting in several approved drugs. Installing a single PEG chain at a defined site in a protein is challenging. Recently, there is has been considerable research into various methods for the site-specific PEGylation of proteins. This review seeks to summarize that work and provide background and context for how site-specific PEGylation is performed. After introducing the topic of site-specific PEGylation, recent developments using chemical methods are described. That is followed by a more extensive discussion of bioorthogonal reactions and enzymatic labeling. 相似文献
96.
Hrvoje Mikulčić Jakov Baleta Xuebin Wang Jin Wang Fengsheng Qi Fan Wang 《International Journal of Hydrogen Energy》2021,46(45):23548-23563
Ammonia appears to be a potential alternative fuel that can be used as a hydrogen vector and fuel for gas turbines and internal combustion engines. Chemical mechanisms of ammonia combustion are important for the development of ammonia combustion systems, but also as a mean of investigation of harmful NOx emissions, so they can be minimized. Despite of large body of experimental and modelling work on the topic of ammonia combustion, there is still need for additional investigation of combustion kinetics.The object of this work is further numerical study of ammonia combustion chemistry under conditions resembling industrial ones. After literature review, three mechanisms of ammonia combustion that also include carbon chemistry are used for simulation of experimental premixed swirl burner with the aim of evaluating their performance. San Diego mechanism, that was also the most detailed one, proved to be the best in terms of emissions, but neither one of the models was able to accurately reproduce CO emission after equivalence ratio went beyond 0.81. It was also observed that oxygen is excessively consumed. This study contributes to the current knowledge by providing new insights in ammonia burning conditions closely resembling those in industrial applications, and consequently is expected that insights obtained will help in the design of real industrial burning systems. 相似文献
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Fundamental developments in nanotechnology have attracted the attention of scientists towards the interaction of nanoparticles due to their fascinating applications in thermal engineering and solar energy systems. Convinced by such motivating applications, the current research project addresses the utilization of nanoparticles in the unsteady three-dimensional chemically reactive flow of an Oldroyd-B fluid induced by a bidirectional oscillatory stretching surface. The effects of mixed convection are also considered here. The prime features of the nanofluid namely thermophoresis and Brownian motion characteristics are explored by introducing the famous Buongiorno's nanofluid model. The relevant equations for the formulated theoretical model have been reduced by the appropriate transformations for which the analytic solution is deliberated via the homotopic technique. Later on, a complete graphical analysis for distinct flow parameters is deliberated for dimensionless velocities, concentration, and temperature distributions with the relevant physical implications. Moreover, stimulating physical quantities like local Nusselt and Sherwood numbers are numerically calculated and discussed. The study emphasizes that decreasing variation in both components of velocities has been reported with an increment of relaxation time, while the impact of the retardation time constant is quite opposite. It is further claimed that the velocity distribution has an increasing tendency in the horizontal direction for a higher buoyancy ratio and mixed convection parameters. Moreover, an increment in thermophoresis parameter enhances both temperature and concentration distributions. 相似文献
100.
Eugenio Meloni Marco Martino Antonio Ricca Vincenzo Palma 《International Journal of Hydrogen Energy》2021,46(26):13729-13747
Hydrogen is a potential green energy vector. Since the heating of the reforming processes commonly used for its production is obtained by burning hydrocarbons, it has a substantial CO2 footprint. One of the most critical aspects in the methane steam reforming (MSR) reaction is the heat transfer to the catalytic volume, due to the high heat fluxes required to obtain high methane conversions. Consequently, the reactor has complex geometries, along with the heating medium being characterized by temperatures higher than 1000 °C; expensive construction materials and high reaction volumes are therefore needed, resulting in slow thermal transients. These aspects increase the costs (both operative and fixed) as well as cause a decrease in the whole process efficiency. The heat transfer limitations due to the endothermicity of methane steam reforming reaction could be effectively overcome by microwave (MW) heating. This heating technique, that depends only on the dielectric properties of the materials, can result in an efficient and faster method for transferring heat directly to the catalyst, thus generating the heat directly inside the catalytic volume. In this work, Ni-based catalysts, differing from each other by the Ni loading (7 and 15 wt% with respect to the washcoat) were prepared. The catalysts were characterized by means of several techniques and tested in the MW-assisted methane steam reforming reaction. Furthermore, the energy balance of the entire process was performed to calculate the energy efficiency, making a preliminary evaluation of its feasibility in distributed hydrogen production also possible. The results of the preliminary tests showed that the prepared structured catalysts are very susceptible to the MW radiation, and that in the presence of the MSR reaction, it is possible to make the system reach a temperature of 900 °C. In the same tests, the CH4 conversion showed a good approach to the thermodynamic equilibrium values starting at temperatures of about 800 °C at a value of gas hourly space velocity (GHSV) of about 5000 h?1. The energy efficiency of the lab-scale system, calculated as the ratio among the energy absorbed by the system and the energy supplied by the microwaves, was about 50%. Future studies will deal with the microwave reactor optimization, aiming at the increase of the energy efficiency of the system, as well as to obtain a higher CH4 conversion at lower temperatures and increase the H2 yield and selectivity. 相似文献